SURFACE MODIFICATION OF STEEL 1.2343 (EN ISO 4957) BY ION NITRIDING

Authors

  • Desislava Dimova Technical University of Sofia, Branch Plovdiv, Center of competence "Smart mechatronic, eco-and energy-saving systems and technologies", Plovdiv, Bulgaria
  • Boyan Dochev Technical University of Sofia, Branch Plovdiv, Center of competence "Smart mechatronic, eco-and energy-saving systems and technologies", Plovdiv, Bulgaria
  • Teodor Solakov Technical University of Sofia, Branch Plovdiv, Plovdiv Bulgaria https://orcid.org/0009-0001-3097-3589
  • Mikaela Dubaradzieva Technical University of Sofia, Branch Plovdiv, Plovdiv Bulgaria https://orcid.org/0009-0009-4336-5994
  • Nikolay Ivanov Technical University of Sofia, Branch Plovdiv, Plovdiv, Bulgaria

DOI:

https://doi.org/10.68302/std2026.vol2.109

Keywords:

coefficient of friction, ion nitriding, microstructure, vacuum quenching and tempering

Abstract

The present study investigates the surface modification of tool steel 1.2343 (EN ISO 4957) by ion nitriding. Prior to the chemical–thermal treatment, the specimens were subjected to heat treatment consisting of vacuum quenching followed by triple tempering, ensuring structural stabilization before the diffusion process. Ion nitriding was carried out under two temperature–time regimes, namely 490°C for 16 h and 500°C for 11 h, in order to evaluate their influence on microstructure, hardness distribution, and tribological behaviour. Microstructural analysis revealed the absence of a compound (white) layer composed of ε and γ′ phases, while a diffusion layer with a relatively uniform thickness of up to ~250 µm was observed. The effect of the nitriding parameters on surface hardness and hardness depth profiles—from the surface to the core—was systematically analyzed. In addition, tribological tests were performed to determine the coefficient of friction and wear characteristics of the treated surfaces. The results indicate that the applied nitriding regimes significantly influence the development of the diffusion layer and the surface properties, with the regime at 500°C providing a more favorable balance between hardness and tribological performance.

Supporting Agencies

This research was funded by the European Regional Development Fund under the Operational Program “Scientific Research, Innovation and Digitization for Smart Transformation 2021-2027”, Project CoC “Smart Mechatronics, Eco- and Energy Saving Systems and Technologies”, BG16RFPR002-1.014-0005.

Downloads

Download data is not yet available.

References

[1] S. Naimi, S. M. Hosseini, “Tool Steels in Die-Casting Utilization and Increased Mold Life”, Advances in Mechanical Engineering, 2015. https://doi.org/10.1155/2014/286071

[2] C. Li, H. Yang, B. Dong, D. Chen, S. Shu, F. Qiu, Q. Jiang, and L. Zhang, “Thermal Fatigue Failure Mechanisms and Enhancement Strategies of Die Steel”, Journal of Materials Research and Technology, vol. 38, pp. 4567–4599, 2025. https://doi.org/10.1016/j.jmrt.2025.08.198

[3] J. Li, Y. Shi, X. Wu, „Effect of Initial Hardness on the Thermal Fatigue Behavior of AISI H13 Steel by Experimental and Numerical Investigations“, Fatigue Fract. Eng. Mater. Struct. 2018, 41, 1260–1274. https://doi.org/10.1111/ffe.12770

[4] D. Klobčar, L. Kosec, B. Kosec, J. Tušek, „Thermo Fatigue Cracking of Die Casting Dies“, Eng. Fail. Anal. 2012, 20, 43–53. https://doi.org/10.1016/j.engfailanal.2011.10.005

[5] K.T. Youn, Y.M. Rhyim, J.H. Lee, C.G. Lee, Y.C. Jung, „An Evaluation of Thermal Fatigue Cracking and Chemical Reaction in Die Casting Mould“, Key Eng. Mater. 2007, 345–346, 701–704. https://doi.org/10.4028/www.scientific.net/KEM.345-346.701

[6] Y. Yuan, W. Wang, M. Zhou, R. Shi, Z. Wang, Y. Zhang, J. Xie, „Microstructure Stability and Softening Resistance of a Novel Cr–Mo–V Hot Work Die Steel“, High Temp. Mater. Process. 2025, 44. https://doi.org/10.1515/htmp-2024-0066

[7] F. Czerwinski, „Thermochemical Treatment of Metals. In Heat Treatment – Conventional and Novel Applications“, InTech: London, UK, 2012. https://doi.org/10.5772/51566

[8] D. Wen, „Plasma Nitriding of Plastic Mold Steel to Increase Wear and Corrosion Properties“, Surf. Coat. Technol. 2009, 204, 511–519. https://doi.org/10.1016/j.surfcoat.2009.08.023

[9] N. Nayebpashaee, M. Soltanieh, S. Kheirandish, „Formation and Growth Mechanism of Nitride Layers during Plasma Nitriding“, Mater. Manuf. Process. 2016, 31, 1192–1200. https://doi.org/10.1080/10426914.2015.1019106

[10] K. Huang, Z. Zheng, C. Lin, W. Huang, J. Zhang, X. Chen, J. Xiao, J. Xu, „Microstructure Characterization and High-Temperature Wear Behavior of Plasma Nitrided Mold Steel“, Surf. Coat. Technol. 2024, 492, 131210. https://doi.org/10.1016/j.surfcoat.2024.131210

[11] D. Wen, „Microstructure and Corrosion Resistance of Plasma-Nitrided Steel. Appl“, Surf. Sci. 2009, 256, 797–804. https://doi.org/10.1016/j.apsusc.2009.08.062

[12] M. Berg, C.V. Budtz-Jørgensen, H. Reitz, K.O. Schweitz, J. Chevallier, P. Kringhøj, J. Bøttiger, „On Plasma Nitriding of Steels. Surf. Coat. Technol“, 2000, 124, 25–31. https://doi.org/10.1016/S0257-8972(99)00472-7

[13] N. Nayebpashaee, H. Vafaeenezhad, S. Kheirandish, M. Soltanieh, „Experimental and Numerical Study on Plasma Nitriding of AISI P20 Steel“, Int. J. Miner. Metall. Mater. 2016, 23, 1065–1075. https://doi.org/10.1007/s12613-016-1324-y

[14] E. Boztepe, A. Alves, E. Ariza, L. Rocha, N. Cansever, F. Toptan, „Corrosion and Tribocorrosion Behaviour of Nitrided Tool Steel“, Surf. Coat. Technol. 2018, 334, 116–123. https://doi.org/10.1016/j.surfcoat.2017.11.033

[15] P. Landgraf, T. Bergelt, L. M. Rymer, C. Kipp, T. Grund, G. Bräuer, T. Lampke, „Evolution of Microstructure and Hardness during Plasma Nitriding“, Metals 2022, 12, 866. https://doi.org/10.3390/met12050866

[16] T. Bergelt, P. Landgraf, T. Grund, G. Bräuer, T. Lampke, „Modelling of Layer Development during Plasma Nitriding“, Surf. Coat. Technol. 2022, 447, 128813. https://doi.org/10.1016/j.surfcoat.2022.128813

[17] M.S. Stechyshyn, A.V. Martynyuk, Y.M. Bilyk, V.P. Oleksandrenko, N.M. Stechyshyna, „Influence of Ionic Nitriding on Structure and Properties“, Mater. Sci. 2017, 53, 343–350. https://doi.org/10.1007/s11003-017-0081-z

[18] A. Gonzalez-Moran, M. Naeem, et al., „Improved Mechanical and Wear Properties of H13 Steel by Plasma Nitriding“, J. Mater. Res. Technol. 2023, 25, 4139–4153. https://doi.org/10.1016/j.jmrt.2023.06.221

[19] Y. Hong, C. Wu, J. Chen, „Precipitation of γ′Nitrides and Its Effect on Nitriding“, J. Alloys Compd. 2019, 792, 818–827. https://doi.org/10.1016/j.jallcom.2019.04.099

[20] W. Chen, C. Wu, Z. Liu, S. Ni, Y. Hong, Y. Zhang, J. Chen, „Phase Transformations in Nitrocarburized Steel“, Acta Mater. 2013, 61, 3963–3972. https://doi.org/10.1016/j.actamat.2013.02.058

[21] S. Bhaskar, H. Kudal, „Tribology of Nitrided-Coated Steel – A Review“, Arch. Mech. Tech. Mater. 2017, 37, 50–57.

[22] J. Peng, Z. Zhu, D. Su, „Sliding Wear of Nitrided H13 Steel“, Tribol. Int. 2019, 232–238. https://doi.org/10.1016/j.triboint.2018.08.017

[23] B. Podgornik, S. Hogmark, O. Sandberg, V. Leskovšek, „Wear Resistance of Duplex Treated Tool Steel“, Wear 2003, 254, 1113–1121. https://doi.org/10.1016/S0043-1648(03)00322-3

[24] K. Das, J. Alphonsa J, M. Ghosh, et al., „Influence of pretreatment on surface behavior of duplex plasma treated AISI H13 tool steel“, Surfaces and Interfaces 2017, Volume 8, pages 206–213 http://dx.doi.org/10.1016/j.surfin.2017.06.009

[25] W. Chen, C. Wu, Z. Liu, S. Ni, Y. Hong, Y. Zhang, J. Chen, „Phase transformations in the nitrocarburizing surface of carbon steels revisited by microstructure and property characterizations“, Acta Materialia 2013, Volume 61, Issue 11, pages 3963-3972. https://doi.org/10.1016/j.actamat.2013.02.058

[26] BDS EN ISO 4957:2018. Tool steels; Bulgarian Institute for Standardization: Sofia, Bulgaria, 2018

[27] BDS EN ISO 6507-1:2024, Metallic materials - Vickers hardness test - Part 1: Test method (ISO 6507-1:2023) European Standard, Bulgarian Institute for Standardization, Sofia, Bulgaria, Feb 19 2024

Downloads

Published

17.09.2026

How to Cite

[1]
D. Dimova, B. Dochev, T. Solakov, M. Dubaradzieva, and N. Ivanov, “SURFACE MODIFICATION OF STEEL 1.2343 (EN ISO 4957) BY ION NITRIDING”, SysTechDev, vol. 2, pp. 67–72, Sep. 2026, doi: 10.68302/std2026.vol2.109.